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Chemistry
Chlorination of benzene in the presence of halogen carrier is an example of
Q. Chlorination of benzene in the presence of halogen carrier is an example of
2233
182
KEAM
KEAM 2010
Hydrocarbons
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A
aromatic nucleophilic substitution
3%
B
aromatic electrophilic substitution
91%
C
aromatic nucleophilic addition
1%
D
aromatic electrophilic addition
2%
E
free radical substitution
2%
Solution:
The chlorination of benzene in the presence of halogen carrier (ie, Lewis acid) is an example of aromatic electrophilic substitution. Mechanism of chlorination is as follows
Cl
−
Cl
+
(
ha
l
o
g
e
n
c
a
rr
i
er
)
F
e
C
l
3
(
e
l
ec
t
ro
p
hi
l
e
)
C
l
+
+
F
e
C
l
4
−