As per the first law of electrolysis, The mass deposited or volume liberated at the electrode is directly proportional to the charge passing between the electrode. m=ZQ
Where Z=FE (electrovalent equivalent) Q=i×t .
mass of O2=FE×i×t (Where F=96500C ) =965008×5×193g =0.08g ∵ At STP , volume of 32gO2=22400mL ∴ The volume of 0.08gO2=3222400×0.08 =56ml