Q.
Calculate the amount of sodium chloride (in g) which must be added to 1000mL of water so that its freezing point is depressed by 0.744K. For water, Kf=1.86K/m. Assume density of water to be 1gmL−1.
Mass of NaCl,w2=?, Volume of water =1000mL, ΔTf=0.744K, Density of water =1gmL−1
So, mass of water W1=1000mL×1gmL−1 =1000g=1kg ΔTf=iKfm=iKf×W1(W258.5)=58.5×W1iKfW2 W2=i×KfΔTf×58.5×1=2×1.860.744×58.5=11.7g
(∵i for NaCl=2)
So, Mass of NaCl required =11,7g.