Q.
Boiling point of water at 750 mm Hg is 96.63∘C. How much sucrose is to be added to 500 g of water such that it boils at 100∘C? Molal elevation constant for water is 0.52Kkgmol−1.
Elevation in boiling point (ΔTb) =Tb−Tb∘=100−96.63=3.37∘C
Mass of solvent (water), W1=500g
Molar mass of solvent, M1=18gmol−1
Molar mass of solute, (C12H22O11),M2=342gmol−1
Mass of sucrose to be added (W2)=? M2=W1ΔTb1000KbW2
From formula, W2=1000×KbM2×W1×ΔTb=1000×0.52342×500×3.37=1108.2g