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Question
Chemistry
Benzyl chloride (C6 H5 CH2 Cl) can be prepared from toluene by chlorination with
Q. Benzyl chloride
(
C
6
H
5
C
H
2
Cl
)
can be prepared from toluene by chlorination with
2920
195
IIT JEE
IIT JEE 1998
Hydrocarbons
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A
S
O
2
C
l
2
22%
B
SOC
l
2
24%
C
C
l
2
46%
D
NaOCl
8%
Solution:
SOC
l
2
,
S
O
2
C
l
2
both give chlorination by nucleophilic substitution on an electrophilic carbon. In toulene, there is no electrophilic centre oxidation occur by controlled free radical reaction using
C
l
2
in presence of high.