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Question
Chemistry
Based on the first law of thermodynamics, which one of the following is correct?
Q. Based on the first law of thermodynamics, which one of the following is correct?
2380
192
KCET
KCET 2010
Thermodynamics
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A
For an adiabatic process :
Δ
E
=
−
q
18%
B
For an isochoric process,
E
=
−
Q
13%
C
For a isothermal process :
E
=
−
Q
15%
D
For a cyclic process,
W
=
−
Q
54%
Solution:
First law of Thermodynamics is
Δ
E
=
Q
+
W
(a) For isochoric process,
Δ
V
=
0
w
=
p
Δ
V
=
0
∴
Δ
E
=
Q
(b) For adiabatic process,
Q
=
0
Δ
E
=
W
(c) For isothermal process,
Δ
T
=
0
and
Δ
E
=
0
Q
=
−
W
(d) For cyclic process, state functions like
Δ
E
=
0
Q
=
−
W