Tardigrade
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Tardigrade
Question
Chemistry
B xleftarrow[ textCatalyst] textLindlar's R - C≡ C - R xrightarrowNa/NH3 A A and B are geometrical isomers (R - CH = CH - R)-
Q.
B
Lindlar’s
Catalyst
R
−
C
≡
C
−
R
N
a
/
N
H
3
A
A and B are geometrical isomers
(
R
−
C
H
=
C
H
−
R
)
−
1915
190
Hydrocarbons
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A
A is trans, B is cis
64%
B
A and B both are cis
7%
C
A and B both are trans
3%
D
A is cis, B is trans
27%
Solution:
Birch reduction gives tram product and Lindlar’s catalyst gives cis product