Aufbau principle does not give the correct arrangement of filling up of atomic orbitals in copper and chromium because half-filled and completely filled electronic configuration of Cr and Cu have lower energy and therefore, more stable. Cr(Z=24):1s2,2s22p6,3s23p63d5,4s1 Cu(Z=29):1s2,2s22p6,3s23p63d10,4s1