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Question
Chemistry
At low pressure and high temperature, the Vander Waal’s equation is finally reduced (simplified) to :
Q. At low pressure and high temperature, the Vander Waal’s equation is finally reduced (simplified) to :
2579
233
UPSEE
UPSEE 2017
States of Matter
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A
P
V
m
=
RT
41%
B
(
P
+
V
m
2
a
)
(
V
m
−
b
)
=
RT
34%
C
P
(
V
m
−
b
)
RT
17%
D
(
P
+
V
m
2
a
)
V
m
=
RT
7%
Solution:
At low pressure and high temperature, van der Waal's equation is modified as :
p
V
m
=
RT
(for 1 mole )
∵
At low pressure and high temperature, the terms
V
2
a
and
b
becomes very small as compared to
p
and
V
.