In solution, CaCl2⟶Ca2++2Cl−i.e, it gives 3 ions. KCl⟶K++Cl−, it gives 2 ions.
Glucose & urea are covalent molecules & do not undergo ionisation.
Since, osmotic pressure is a colligative property & depends upon the number of solute particles 0.1M CaCl2 exhibits highest osmotic pressure.