Q.
At 25∘C, at 5% aqueous solution of glucose (molecular weight =180gmol−1 ) is isotonic with a 2% aqueous solution containing and unknown solute. What is the molecular weight of the unknown solute?
Since the two solutions are isotonic, they must have same concentrations in moles/litre. For glucose solution, concentration =5g/100cm3 (given) =50g/L ∴18050=M20
or M=72
( ∵ Molar mass of glucose =180gmol−1 )
For unknown substance, concentration =2g/100cm3 (given) =20g/L=M20mol/L ∴18050=M20 or M=72