Q.
Assertion : The increase in internal encrgy (ΔE) for the vapourization of one mole of water at 1 atm and 373K is zero. Reason : For all isothermal processes, ΔE=0.
At 373K or 100∘C, the water starts boiling and at this temperature the vaporization of water is an isothermal process.
The internal energy change (ΔE), depend only on temperature, it follows that at constant temperature, the internal energy of the gas remains constant, i.e. ΔE is zero.