Q. Assertion : Spontaneous process is an irreversible process and may be reversed by some external agency.
Reason : Decrease in enthalpy is a contributory factor for spontaneity.

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Solution:

A process is spontaneous when .

When , it may lead to negative value for .
A spontaneous process is an irreversible process and may be reversed by some external agency.
The decrease in enthalpy is a contributory factor for spontaneity.