Q.
Assertion : SeCl4 does not have a tetrahedral structure. Reason : Se in SeCl4 has two lone pairs.
1911
168
AIIMSAIIMS 2008Chemical Bonding and Molecular Structure
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Solution:
SeCl4 possesses see-saw geometry, which can be regarded as a distorted trigonal bipyramidal structure, having one lone pair of electrons in the basal position of the trigonal bipyramid. See-saw geometry of SeCl4 molecules arises due to the sp3d hybridisation of the central atom. The distortion in shape is due to the presence of one lone pair of electrons.