Catalytic activity of transition metals is due to their ability to adopt multiple oxidation states and form complexes. Iron(III) catalyses the reaction between iodide and persulphate ions. 2I−+S2OB2−→I2+2SO42−
This can be explained as : 2Fe3++2F→2Fe2++I2 2Fe2++S2O82−→2Fe3++2SO42−