Q.
Assertion In the Lyman series of H-spectra, the maximum wavelength of lines is 121.65 nm. Reason Wavelength is maximum if there is transition from the very next level.
λ1=RHZ2[n121−n221] For Lyman series, n1=1 and n2=2 [ ∵ for maximum λ, transition is from very next level.] ∴λ1=109678×(1)2[(1)21−(2)21]cm−1 or =4109678×3cm−1λ=3×1096784×107×10−7cm=121.65nm.