Q. Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling points either greater than both the components or lesser than both the components.
Reason : The composition of the vapour phase is same as that of the liquid phase of an azeotropic mixture.

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Solution:

Non-ideal solutions with positive deviation i.e., having more vapour pressure than expected, boil at lower temperature while those with negative deviation boil at higher temperature than those of the components.