Q. Assertion : Aryl halides cannot be prepared by replacement of hydroxyl group of phenol by halogen atom.
Reason: Phenols react with halogen acids violently.

 5504  208 Haloalkanes and Haloarenes Report Error

Solution:

Aryl halides cannot be prepared by replacing hydroxyl group of phenols because the carbon oxygen bond in phenols has a partial double bond character and is difficult to break being stronger than a single bond.