Assertion (A) - NH 2 group of aniline is ortho, para directing in electrophilic substitutions. Reason (R) - NH 2 group stabilises the arenium ion formed by the ortho, para attack of the electrophile. The correct answer is

Question

Assertion (A) - NH 2 group of aniline is ortho, para directing in electrophilic substitutions. Reason (R) - NH 2 group stabilises the arenium ion formed by the ortho, para attack of the electrophile. The correct answer is (A) Both (A) and (R) are correct, (R) is the correct explanation of (A) (B) Both (A) and (R) are correct, (R) is not the correct explanation of (A) (C) (A) is correct, but (R) is not correct (D) (A) is not correct, but (R) is correct

Tardigrade Admin · Accepted Answer

The - NH 2 group of aniline is a very strong electron donor (+M effect), hence it activates the benzene ring thoroughly and the electrophilic aromatic substitutions on the benzene ring are very easy to take place at ortho and para-positions.

In addition to the usual resonating structures, that stabilizes the intermediate carbonium ion, the resonating strucutres formed by the interaction of lone pair electrons of nitrogen with the positively charged carbon of the ring also increase the stability of the carbonium ion formed during the atttack of Br + ion (electrophile) on O - and p -positions.

Q. Assertion (A) −NH2​ group of aniline is ortho, para directing in electrophilic substitutions. Reason (R) −NH2​ group stabilises the arenium ion formed by the ortho, para attack of the electrophile. The correct answer is

Both (A) and (R) are correct, (R) is the correct explanation of (A)

Both (A) and (R) are correct, (R) is not the correct explanation of (A)

(A) is correct, but (R) is not correct

(A) is not correct, but (R) is correct

Q. Assertion (A) $- N H_{2}$ group of aniline is ortho, para directing in electrophilic substitutions.
Reason (R) $- N H_{2}$ group stabilises the arenium ion formed by the ortho, para attack of the electrophile.
The correct answer is