Q. Arrange the following nucleophiles in the decreasing order of nucleophilicity :Chemistry Question Image

 2207  202 AIIMSAIIMS 2017Organic Chemistry – Some Basic Principles and Techniques Report Error

Solution:

Conjugate base (nucleophile) is strong if acid is weak and vice-versa.
(B) CH3O- is a conjugate base of CH3OH (II).
(C) CN- is a conjugate base of HCN (III).
Order of acidic nature is IV > I > III > II.
Hence, the decreasing order of nucleophilicity is B > C > A > D.

Solution Image Solution Image