Q.
An unknown compound A has a molecular formula C4H6, when A is treated with an excess of Br2, a new substance B with formula C4H6Br4 is formed. A forms a white precipitate with ammoniacal silver nitrate solution. A may be
: Since A (C4H6) adds two moles of Br2 to give B (C4H6Br4) therefore, it is a butyne. Further since A forms a white ppt. with ammoniacal AgNO3 solution therefore, A is 1-butyne. CH3CH2C≡CH+AgNO3+NH4OH(whiteppt.)CH3CH2C≡CAg+NH4NO3+H2O