An organic compound X when exposed to sunlight and air, slowly decomposes into a poisonous gas Y and HCl. To prevent from decomposition X is stored in dark brown coloured bottle and in 1 % ethyl alcohol. This retards the decomposition and converts Y into harmless Z. Identify X, Y and Z

Question

An organic compound X when exposed to sunlight and air, slowly decomposes into a poisonous gas Y and HCl. To prevent from decomposition X is stored in dark brown coloured bottle and in 1 % ethyl alcohol. This retards the decomposition and converts Y into harmless Z. Identify X, Y and Z (A) CCl 4, COCl 2, C 2 H 5 CO 3 (B) CHCl 3, COCl 2,( C 2 H 5)2 CO 3 (C) CCl 4, CO 2,( C 2 H 5)2 CO 3 (D) CHCl 3, COCl 2, C 2 H 6 CO 3

Tardigrade Admin · Accepted Answer

C undersetXHCl 3+[ O ] arrow C undersetYOCl 2+ HCl COCl 2+2 C 2 H 5 OH longrightarrow ( C 2 undersetZH 5)2 CO 3+2 HCl

$CC l_{4}, COC l_{2}, C_{2} H_{5} C O_{3}$

$C H C l_{3}, COC l_{2}, (C_{2} H_{5})_{2} C O_{3}$

$CC l_{4}, C O_{2}, (C_{2} H_{5})_{2} C O_{3}$

$C H C l_{3}, COC l_{2}, C_{2} H_{6} C O_{3}$

$C X H C l_{3} + [O] \to C Y O C l_{2} + H Cl$

$COC l_{2} + 2 C_{2} H_{5} O H ⟶ (C_{2} Z H_{5})_{2} C O_{3} + 2 H Cl$

Q. An organic compound X when exposed to sunlight and air, slowly decomposes into a poisonous gas Y and HCl. To prevent from decomposition X is stored in dark brown coloured bottle and in 1% ethyl alcohol. This retards the decomposition and converts Y into harmless Z. Identify X,Y and Z

CCl4​,COCl2​,C2​H5​CO3​

CHCl3​,COCl2​,(C2​H5​)2​CO3​

CCl4​,CO2​,(C2​H5​)2​CO3​

CHCl3​,COCl2​,C2​H6​CO3​

CXH​Cl3​+[O]→CYO​Cl2​+HCl COCl2​+2C2​H5​OH⟶(C2​ZH5​)2​​CO3​+2HCl

$CC l_{4}, COC l_{2}, C_{2} H_{5} C O_{3}$

$C H C l_{3}, COC l_{2}, (C_{2} H_{5})_{2} C O_{3}$

$CC l_{4}, C O_{2}, (C_{2} H_{5})_{2} C O_{3}$

$C H C l_{3}, COC l_{2}, C_{2} H_{6} C O_{3}$

$C X H C l_{3} + [O] \to C Y O C l_{2} + H Cl$

$COC l_{2} + 2 C_{2} H_{5} O H ⟶ (C_{2} Z H_{5})_{2} C O_{3} + 2 H Cl$