Q.
An organic compound of molecular formula C3H6O did not give a silver mirror with Tollens’ reagent but give an oxime with hydroxylamine. It may be
3019
197
Aldehydes Ketones and Carboxylic Acids
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Solution:
Aldehydes give silver mirror test with Tollens' reagent while ketones form oximes with hydroxylamine. Hence the compound is a ketone. Alcohol and ethers do not give this test.