Q.
An organic compound is estimated through Dumas method and was found to evolved
6 moles of CO2,4 moles of H2O and 1 mole of nitrogen gas. The formula of the compound is
252
127
Organic Chemistry – Some Basic Principles and Techniques
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Solution:
In Dumas method, organic compound is heated with dry cupric oxide in a combustion tube in the atmosphere of CO2. Upon heating, C and H present are oxidised to CO2 and water vapours while N2 is set free.
Let, the molecular formula of the organic compound ( 1mol) be CxHvNz. In Dumas method,