An organic compound [ A ]( C 4 H 11 N ), shows optical activity and gives N 2 gas on treatment with HNO 2. The compound [ A ] reacts with PhSO 2 Cl producing a compound which is soluble in KOH. The structure of A is:

Question

An organic compound [ A ]( C 4 H 11 N ), shows optical activity and gives N 2 gas on treatment with HNO 2. The compound [ A ] reacts with PhSO 2 Cl producing a compound which is soluble in KOH. The structure of A is: (A)  (B)  (C)  (D)

Tardigrade Admin · Accepted Answer

C 4 H 11 N releases N 2 with HNO 2 i.e. it is primary amine. After reacting with Hinsberg reagent it forms a compound which is soluble in KOH, Hence, the amine is primary.

Q. An organic compound $[A] (C_{4} H_{11} N)$ , shows optical activity and gives $N_{2}$ gas on treatment with $H N O_{2}$ . The compound $[A]$ reacts with $P h S O_{2} Cl$ producing a compound which is soluble in $K O H$ . The structure of $A$ is:

$C_{4} H_{11} N$ releases $N_{2}$ with $H N O_{2}$ i.e. it is primary amine.
After reacting with Hinsberg reagent it forms a compound which is soluble in $K O H$ , Hence, the amine is primary.

Q. An organic compound [A](C4​H11​N), shows optical activity and gives N2​ gas on treatment with HNO2​. The compound [A] reacts with PhSO2​Cl producing a compound which is soluble in KOH. The structure of A is:

C4​H11​N releases N2​ with HNO2​ i.e. it is primary amine. After reacting with Hinsberg reagent it forms a compound which is soluble in KOH, Hence, the amine is primary.

Q. An organic compound $[A] (C_{4} H_{11} N)$ , shows optical activity and gives $N_{2}$ gas on treatment with $H N O_{2}$ . The compound $[A]$ reacts with $P h S O_{2} Cl$ producing a compound which is soluble in $K O H$ . The structure of $A$ is:

$C_{4} H_{11} N$ releases $N_{2}$ with $H N O_{2}$ i.e. it is primary amine.
After reacting with Hinsberg reagent it forms a compound which is soluble in $K O H$ , Hence, the amine is primary.