Q. An insulated system contains moles of an ideal diatomic gas at temperature . When a heat is supplied to the gas, moles of the gas is dissociated into atoms and the temperature remained constant.Then the relation between and is universal gas constant.

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Solution:

Given, number of moles of an ideal diatomic gas at the temperature,
When heat is supplied to the gas, mole of the gas is dissociated into atoms and the temperature remains constant, therefore heat supplied = change in its internal energy
i.e.,
or (internal energy of 4 moles of a monatomic gas internal energy of moles of diatomic gas ) - (internal energy of 4 moles of a diatomic gas)