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Q. An insulated system contains $4$ moles of an ideal diatomic gas at temperature $T$. When a heat $Q$ is supplied to the gas, $2$ moles of the gas is dissociated into atoms and the temperature remained constant.Then the relation between $Q$ and $T$ is $( R =$ universal gas constant. $)$

AP EAMCETAP EAMCET 2019

Solution:

Given, number of moles of an ideal diatomic gas at the temperature, $T=4$
When heat $Q$ is supplied to the gas, $2$ mole of the gas is dissociated into atoms and the temperature remains constant, therefore heat supplied = change in its internal energy
i.e., $Q=\Delta u=\left(u_{f}-u_{i}\right)$
or $Q=$ (internal energy of 4 moles of a monatomic gas $+$ internal energy of $2$ moles of diatomic gas ) - (internal energy of 4 moles of a diatomic gas)
$=\left(4 \times \frac{3}{2} R T+2 \times \frac{5}{2} R T\right)-\left(4 \times \frac{5}{2} R T\right)$
$=6 \,R T+5\, R T-10 \,R T=R T$