Q.
An element crystallises in a structure having an fcc unit cell of an edge length 100pm. If 25g of the element contains 25×1024 atoms, the density of the element is ____ gcm−3.
100pm=100×10−10cm
Volume of unit cell =(100×10−10)3 =1×10−24cm3
Mass of an atom =25×102425=1×10−24g
No. of atoms in an fcc unit cell =4
Mass of unit cell =4×1×10−24 =4×10−24g
Density = Volume Mass =1×10−244×10−24=4gcm−3