We know that, direction of propagation of electromagnetic wave is always along the direction of vector product (E×B) B=Bj^=B(k^×i^)=cE(k^×i^) ⇒B=c1[k^×Ei^]=c1[k^×E]
If we write the equation in terms of magnetic field, then E=c(B×k). k^⋅E=k^⋅(Ei^)=0, k^⋅B^=k^⋅(Bj^)=0,
as angle between them is 90∘.