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Tardigrade
Question
Chemistry
Amongst the following, the compound that can most readily get sulphonated is
Q. Amongst the following, the compound that can most readily get sulphonated is
1153
189
MGIMS Wardha
MGIMS Wardha 2014
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A
benzene
B
toluene
C
nitrobenzene
D
chlorobenzene
Solution:
In toluene,
(
−
C
H
3
)
group is present which has
+
I
effect and increase electron density on ortho and para position. While in sulphonation
−
S
O
3
H
acts as electrophile. Therefore, it
(
−
S
O
3
H
)
attacks on ortho and para position readily.