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Tardigrade
Question
Chemistry
Among the following which are ambidentate ligands? (i) NO-2 (ii) NO-3 (iii) EDTA4- (iv) C2O2-4 (v) SCN- (vi) H2NCH2CH2NH2
Q. Among the following which are ambidentate ligands?
(i)
N
O
2
−
(
ii
)
N
O
3
−
(iii)
E
D
T
A
4
−
(
i
v
)
C
2
O
4
2
−
(v)
SC
N
−
(
v
i
)
H
2
NC
H
2
C
H
2
N
H
2
4294
232
KEAM
KEAM 2008
Coordination Compounds
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A
(i) and (ii)
19%
B
(iii) and (iv)
17%
C
(i) and (vi)
12%
D
(iii) and (vi)
17%
E
(i) and (v)
17%
Solution:
The ligands which have two coordination positions but can coordinate to the central metaI ion through only one coordination position at a time, are called ambidentate Iigand,
e.g.,
C
N
−
,
CN
S
−
,
N
O
2
−
.