Q.
Among the following the third ionization energy is highest for
3106
209
AMUAMU 2010Classification of Elements and Periodicity in Properties
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Solution:
The electronic configuration of the given elements is as 12Mg=[Ne]3s2 5B=[He]2s2,2p1 4Be=[He]2s2 13Al=[Ne]3s23p1
From the electronic configuration, it is clear that third ionisation energy of Mg and Be is higher as compared to Al and B as in them the third electron have to be removed from the stable inert gas configuration.
Between Mg and Be, third IE of Be is higher because of its smaller size.