The principle of conductometric titration is based on the fact that during
the titration one of the ions is replaced by other and invariably these two ions differ in the ionic conductivity.
In the conductometric titration of 0.05MH2SO4 with 0.1MNH4OH, initially the fast moving H+ ion get neutralised as H2O and is replaced by slow moving NH4+ ion upto neutralisation point. After neutralisation point, weak electrolyte NH4OH is added gradually, which do not affect the conductance. Thus, plot (b) is the correct one.