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Question
Chemistry
Among the following, the number of compounds that can react with PCl5 to give POCl3 is O2,C O2,S O2,H2O, H2SO4,P4O10.
Q. Among the following, the number of compounds that can react with
PC
l
5
to give
POC
l
3
is
O
2
,
C
O
2
,
S
O
2
,
H
2
O
,
H
2
S
O
4
,
P
4
O
10
.
1835
213
IIT JEE
IIT JEE 2011
The p-Block Elements - Part2
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Answer:
4
Solution:
PC
l
5
produces
POC
l
3
with the following reagents
PC
l
5
+
S
O
2
⟶
POC
l
3
+
SOC
l
2
PC
l
5
+
H
2
O
⟶
POC
l
3
+
2
H
Cl
2
PC
l
5
+
H
2
S
O
4
⟶
S
O
2
Cl
,
+
2
POC
l
3
+
2
H
Cl
6
PC
l
5
+
P
4
O
10
⟶
10
POC
l
3