2 and 6 are ortho position 4 is para position 3 and 5 are meta position with respect to the substituent - X.
Aromatic compounds undergo eiectrophilic substitution reaction.
Those groups which increase the electron density on ortho, para position (viz,−CH3,−C2H5,−OH,−Br,−NH2,−NH R etc.)
are called ortho/para directing group substituents, which increases electron density on meta position (−NO2,−CN,−CHO,−COR.−COOH,−COOR,−SO3H etc.) are meta directing groups.