Amides are less basic than amines because

Question

Amides are less basic than amines because (A) a carbonyl group, donates electrons by resonance (B) the carbonyl group withdraws electrons by resonance (C) nitrogen does not have a lone pair of electrons (D) nitrogen has a full positive charge

Tardigrade Admin · Accepted Answer

R- oversetO mathop overset|| mathopC - oversetnterdot nterdot mathopN H2rightarrow R- oversetO- mathop overset| mathopO = overset+ mathopN H2 Resonance decreases electron donating ability of nitrogen hence basic strength of amide compared to amines also decreases

Q. Amides are less basic than amines because

a carbonyl group, donates electrons by resonance

the carbonyl group withdraws electrons by resonance

nitrogen does not have a lone pair of electrons

nitrogen has a full positive charge

$R - C ∣∣ O - N \cdot \cdot H_{2} \leftrightarrow R - O ∣ O^{-} = N + H_{2}$ Resonance decreases electron donating ability of nitrogen hence basic strength of amide compared to amines also decreases

Q. Amides are less basic than amines because

a carbonyl group, donates electrons by resonance

the carbonyl group withdraws electrons by resonance

nitrogen does not have a lone pair of electrons

nitrogen has a full positive charge

R−C∣∣O−N⋅⋅H2​↔R−O∣O−=N+H2​ Resonance decreases electron donating ability of nitrogen hence basic strength of amide compared to amines also decreases

$R - C ∣∣ O - N \cdot \cdot H_{2} \leftrightarrow R - O ∣ O^{-} = N + H_{2}$ Resonance decreases electron donating ability of nitrogen hence basic strength of amide compared to amines also decreases