The reagent used to distinguish aldehydes and ketones is one with which either aldehyde or ketone reacts.
[a] Lucas test: It is used to distinguish between 1∘,2∘ and 3∘ alcohols.
The Lucas reagent is anhydrous ZnCl2 and cone. HCl.
[b] Tollens reagent: It is ammoniacal silver nitrate solution. Aldehydes reduce it to silver mirror whereas ketones dont react with it.
So, Tollens reagent is used to distinguish between aldehydes and ketones.
[c] Molisch test: It is used to detect the presence of carbohydrate in solution. Formation of violet coloured ring at the junction of ale. a-naphthol solution and cone. H2SO4 shows the presence of carbohydrate in the food.