When cold H2O2 is added in cold mixture of K2Cr2O7 and conc. H2SO4 (i.e. K2Cr2O7 in acidic medium), a deep blue solution of blue perchromate is obtained as, K2Cr2O7+H2SO4→K2SO4+H2Cr2O7 H2Cr2O7+4H2O2→Blue per chromate2CrO5+5H2O