Q.
A vessel contains a mixture of one mole of oxygen and two moles of nitrogen at 300K . The ratio of the average rotational kinetic energy per O2 molecule to per N2 molecule is
Average kinetic energy per molecule per degree of freedom =21kT . Since, both the gases are diatomic and at the same temperature (300K) , both will have the same number of rotational degree of freedom i.e., two. Therefore, both the gases will have the same average rotational kinetic energy per molecule =2×21kT=kT . Thus, ratio will be 1:1 .