Q.
A spherical balloon of 21cm diameter is to be filled up with H2 at NTP from cylinder containing the gas at 20atm at 27∘C. The cylinder can hold 2.82 litre of water a NTP. Calculate the number of balloons that can be filled up.
Volume of one balloon (to be filled) 34πr3=34×722×2213 =4851mL=4.851 litre
Let ' n ' balloons are filled, then total volume of H2 used in filling balloons =4.851×n litre
The cylinder of H2 used in filling balloons will
also have H2 in it, after n balloons are filled.
Also volume of cylinder =2.82 litre
Hence, Total volume of H2 at NTP = volume
of ' n ' balloons + volume of cylinder =4.851×n+2.82…...(i)
The volume of available H2 at NTP can be
derived by the data
Given P=1atm,V=?,T=273K
and P=20atm,V=2.82 litre, T=300K ∴T1P1V1=T2P2V2
or 2731×V=30020×2.82 ∴V=30020×2.82×273=51.32...(ii)
From equation (1) and (II) 4.851×n+2.82=51.32 n=10