Q.
A sample of O2 gas is collected over water at 23∘C at a barometric pressure of 751mmHg (vapour pressure of water at 23∘C is 21mmHg).The partial pressure of O2 gas in the sample collected is
Using the Dalton's law
P (Total) = Poxygen +Pwater
The vapor pressure of water is 21mmHg 751mmHg= Poxygen +21mmHg
Poxygen =751mmHg−21mmHg
Poxygen =730mmHg
Convert the partial pressure of oxygen in to atmosphere (730mmHg)(1atm/760mmHg)=0.96atm