There are two different reactants (say A and B). A+B→ product
Thus it is a bimolecular reaction.
If dtdx=k[A][B]
it is second-order reaction
If (dtdx)=k[A]
or=k[B]
it is first order reaction.
Molecularity is independent of rate, but is the sum of the reacting substances thus it cannot be unimolecular reaction.