Given, cell is fcc. So, Z=4
Edge length, a=404pm=4.04×10−8cm
Density of metal, d=2.72g/cm3 NA=6.02×1023mol−1
Molar mass of the metal, M= ?
We know that density, d=a3⋅NAZ×M ⇒M=Zd⋅a3NA =42.72×(4.04×10−8)3×6.02×1023 =27g/mol ∴ Atomic mass of copper (Cu)=63.1u.