Here, C=37.55Jmole−1K−1; and PT=K (constant) ...(i)
According to standard gas equation PV=RT or P=RT/V
From (i), VRT×T=K or V=KRT2 ∴dtdV=K2RT
But KT=P1 rom eqn. (i), therefore, dTdV=P2R...(ii)
As, C=Cv+PdTdV, therefore, using (ii) C=Cv+P×P2R=Cv+2R or Cv=C−2R
As, Cv=2nR ∴2nR=C−2R or n=R2(C−2R)=8.32(37.55−2×8.3)=5