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Chemistry
A fuel cell involves combustion of the butane at 1 atm and 298 K, C4H10(.g.)+(13/2)O2(.g.) arrow 4CO2(.g.)+5H2O(.l.) Δ G° =-2746 kJ/mol What is E° of a cell?
Q. A fuel cell involves combustion of the butane at 1 atm and 298 K,
C
4
H
10
(
g
)
+
2
13
O
2
(
g
)
→
4
C
O
2
(
g
)
+
5
H
2
O
(
l
)
Δ
G
∘
=
−
2746
k
J
/
m
o
l
What is
E
∘
of a cell?
2504
236
NTA Abhyas
NTA Abhyas 2020
Electrochemistry
Report Error
A
+4.74 V
0%
B
+0.547 V
0%
C
+1.09 V
100%
D
+4.37 V
0%
Solution:
In the reaction
C
4
H
10
(
g
)
−
10
+
10
+
2
13
O
2
(
g
)
→
4
C
O
2
(
g
)
+
4
−
4
+
5
H
2
O
(
l
)
Change in oxidation number of carbon
=
+
16
−
(
−
10
)
=
+
26
So number of electrons involved in cell process will be 26.
E
∘
=
n
F
−
Δ
G
∘
=
26
×
96500
(
−
2746
)
×
1000
=
+
1.09
V