Q.
A 5.82g silver coin is dissolved in nitric acid. When sodium chloride is added to the solution, all the silver is precipitated as AgCl . The AgCl precipitate weighs 7.20g . The percentage of silver in the coin is
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AMUAMU 2014Some Basic Concepts of Chemistry
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Solution:
Silver solution in HNO3+NaCl→108+35.5AgCl
Atomic mass of Ag=108g=143.5
Weight of Ag=5.82g ∵143.5gAgCl is obtained from Ag=108g ∴7.20gAgCl will be obtained from Ag =143.5108×7.20=5.418g
Weight of Ag taken =5.82 % purity =5.825.418×100 =93.09%