Q.
84Po210 decays with a particle to 82Pb206 with a half-life of 138.4 days. If 1.0 g of 84Po210 is placed in a sealed tube, how much helium will accumulate in 69.2 days. Express the answer in cm3 at STP.
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NTA AbhyasNTA Abhyas 2020Surface Chemistry
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Solution:
t1/2=138.4 days, t = 69.2 day
Number of half-lifes n=t1/2t=138.469.2=21
Amount of Po left 21 after half-life =(2)1/21g=0.707g
Amount of Po used in 21 half-life =1−0.707=0.293g
Now 84Po210→82Pb206+2He4
210 g Po on decay will produce = 4g He
0.293 g Po on decay will produce =2104×0.293=5.581×10−3gHe
Volume of He at STP =45.581×10−3×22400=31.25mL=31.25cm3