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Question
Chemistry
Half-life period of the first order reaction is 100 days. After 144.3 days, concentration of the reactant is reduced to ldots ldots of the original value.
Q. Half-life period of the first order reaction is
100
days. After
144.3
days, concentration of the reactant is reduced to
……
of the original value.
2362
259
Chemical Kinetics
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A
e
2
1
8%
B
e
1
67%
C
20%
25%
D
10%
0%
Solution:
T
50
=
k
0.693
∴
k
=
t
50
0.693
=
100
0.693
day
−
1
k
1
=
0.693
100
=
1.44.3
days
=
Average life
Thus, given time
t
=
k
1
(Average life)
C
=
C
o
e
−
k
t
=
C
o
e
−
k
/
k
=
e
C
o
Thus, concentration is reduced to
(
e
1
)
of the initial value.