Sulphur burns in oxygen according to the following equation 32gS+O2⟶SO2+ΔHf 0.5g S liberate =4.6kJ heat 1gS liberate =0.54.6kJ 32gS will liberate =0.54.6×32 =294.4kJ
Heat of formation is the amount of heat liberated or absorbed when one mole of compound is formed from its constituent elements hence,
Heat of formation of SO2=−294.4kJ