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Question
Chemistry
2,3- dibromobutane can be converted to 2-butyne in a two steps reaction using
Q.
2
,
3
−
dibromobutane can be converted to
2
-butyne in a two steps reaction using
1633
157
KVPY
KVPY 2016
Hydrocarbons
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A
(i) HCl and (ii) NaH
0%
B
(i) alc. KOH and (ii)
N
a
N
H
2
100%
C
(i) Na and (ii) NaOH
0%
D
(i)
B
r
2
and (ii) NaH
0%
Solution:
For the conversion of
2
,
3
−
dibromobutane to
2
−
butyne following steps can be used
In this step, dehydrohalogenation occurs where
2
,
3
dibromobutane gets converted into
2
−
bromobut
−
2
−
ene
In this step, also dehydrohalogenation occurs where alkenyl halide on treatment with soda amide gives
2
−
butyne